Search results for "β irradiation"

showing 2 items of 2 documents

Intrinsic defects induced by β-irradiation in silica

2002

We report an electron paramagnetic resonance study of defects induced by β-irradiation in natural and synthetic samples of high purity commercial silica. Data are collected for the E′ centers and a resonance satellite signal split by 1.36 mT. By comparison with the effects of γ-irradiation it is shown that the mechanisms of defect generation are the same for the two irradiation sources and that in the high-dose limit they involve intrinsic defects of the glassy matrix. Moreover, the high concentration of defects generated by β-irradiation modifies the EPR spectrum due to spin–spin interaction.

High concentrationNuclear and High Energy PhysicsMaterials sciencePhysics::Medical Physicsβ irradiationResonancePhotochemistryCrystallographic defectlaw.inventionNuclear magnetic resonancelawGlassy matrixIrradiationElectron paramagnetic resonanceInstrumentationNuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms
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Photoluminescence properties of S2 molecule trapped in Melanophlogite

2015

We studied the photoluminescence properties of a sample of SiO2-clathrate Melanophlogite, a crystalline microporous material which is found in nature as a rare mineral. Upon β irradiation, the material displays an intense light emission under near-UV illumination. We studied in detail this optical activity by steady-state and time-resolved photoluminescence measurements as a function of temperature. The spectroscopic properties we find can be ascribed to a population of quasi-free molecules trapped within each of the two different types of cage available in the structure of this clathrate, although the spectroscopic properties of the guest molecules are affected by their interactions with t…

β IrradiationPhotoluminescenceClathrate hydratePopulation02 engineering and technologyengineering.material010402 general chemistry01 natural sciencesGeochemistry and PetrologyMoleculeGeneral Materials ScienceClathrateeducationPhotoluminescenceeducation.field_of_studyS2 moleculeChemistryMicroporous material021001 nanoscience & nanotechnology0104 chemical sciencesChemical physicsMelanophlogiteMelanophlogiteExcited stateengineeringLight emissionMaterials Science (all)Atomic physics0210 nano-technology
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